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21.
Jingwen Mao Jiandong Zhang Franco Pirajno Daizo Ishiyama Huimin Su Chunli Guo Yuchuan Chen 《Ore Geology Reviews》2011,43(1):203-216
Based on previous studies and detailed field investigations of the Dexing porphyry copper deposit, the Yinshan Ag-Pb-Zn deposit and the Jinshan shear zone – hosted gold deposit in the Dele Jurassic volcanic basin, in the northeastern Jiangxi province, East China, we propose that the three deposits share spatial, temporal and genetic relationships and belong to the same metallogenic system. Dexing is a typical porphyry Cu–Au–Mo deposit in which both ore-forming fluid and metals are derived from the granite porphyry. The Yinshan deposit consists of a porphyry copper ore located in the cupola of a quartz porphyry stock, in the lower part, and Ag–Pb–Zn ore veins in the upper part. The hydrothermal fluids were mainly derived from the magma in the early stages of the mineralizing event and became mixed with meteoric waters in the late stages. Its ore metals are magma-derived. Both the Jinshan base metal veins and the Hamashi, Dongjie and Naikeng quartz vein-type gold deposit are hosted by brittle–ductile structures, which are distal in relation to the porphyry intrusions and were formed by mixed magmatic fluids and meteoric water, whereas the gold was mainly leached from the country rocks (Mesoproterozoic Shuangqiaoshan Group phyllite and schist). The deposits show a distinct spatial arrangement from porphyry Cu, to epithermal Ag–Pb–Zn and distal Au. We suggest a porphyry–epithermal–distal vein ore system model for this group of genetically related mineral deposits. They were formed in a back-arc setting in a Middle Jurassic active continental margin, with magmas derived from the subducted slab. 相似文献
22.
Kaul Gena Hitoshi Chiba Katsuo Kase Kazuo Nakashima Daizo Ishiyama 《Resource Geology》2013,63(4):360-370
A sulfide chimney ore sampled from the flank of the active Tiger vent area in the Yonaguni Knoll IV hydrothermal field, south Okinawa trough, consists of anhydrite, pyrite, sphalerite, galena, chalcopyrite and bismuthinite. Electron microprobe analysis indicates that the chalcopyrite contains up to 2.4 wt% Sn, whereas bismuthinite contains up to 1.7 wt% Pt, 0.8 wt% Cu and 0.5 wt% Fe. The Sn‐rich chalcopyrite and Pt–Cu–Fe‐bearing bismuthinite are the first reported occurrence of such minerals in an active submarine hydrothermal system. The results confirm that Sn enters the chalcopyrite as a solid solution towards stannite by the coupled substitution of Sn4+Fe2+ for Fe3+Fe3+, whereas Pt, Cu and Fe enter the bismuthinite structure as a solid solution during rapid nucleation. The fluid inclusions homogenization temperatures in anhydrite (220–310°C) and measured end‐member temperature of the vent fluids on‐site (325°C) indicate that Sn‐bearing chalcopyrite and Pt–Cu–Fe‐bearing bismuthinite express the original composition of the minerals that precipitated as metastable phases at a temperature above 300°C. The result observed in this study implies that sulfides in ancient volcanogenic massive sulfide deposits have similar trace element distribution during nucleation but it is remobilised during diagenesis, metamorphism or supergene enrichment processes. 相似文献
23.
Yuji Ishiyama 《地震工程与结构动力学》1982,10(5):635-650
This investigation deals with motions of rigid bodies on a rigid floor subjected to earthquake excitations, and criteria for overturning of the bodies. In order to study any motions of a body in a plane, the motions are classified into six types, i.e. (1) rest, (2) slide, (3) rotation, (4) slide rotation, (5) translation jump and (6) rotation jump. Then, the following are studied: the equations of motion, transitions of motion, and motions after impact between the body and the floor. One of the features of this investigation is the introduction of the tangent restitution coefficient which enables us to estimate the magnitude of the tangent impulse at the instant of impact. A computer program was developed to simulate the motions of bodies subjected to horizontal and vertical ground motions, numerically solving the non-linear equations of motion. Several types of simulation were carried out and the following conclusions were found. The coefficient of friction must be greater than the breadth—height-ratio in order for the body to rock. The motions after impact from translation jump are greatly influenced by the normal and tangent restitution coefficients. As criteria for overturning of bodies, at least two factors must be taken into account: the horizontal acceleration and the velocity of the floor. Then it is possible to estimate the motions of the floor from the overturning of bodies in a more reliable manner than before. 相似文献
24.
Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m) maintained at 70°C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH− neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH > 10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past. 相似文献
25.
Formation of a third volcanic chain in Kamchatka: generation of unusual subduction-related magmas 总被引：2，自引：0，他引：2
Yoshiyuki Tatsumi Tetsu Kogiso Susumu Nohda 《Contributions to Mineralogy and Petrology》1995,120(2):117-128
The unusual development of three volcanic chains, all parallel to the trend of the subduction trench, is observed in Kamchatka at the northern edge of the Kurile arc. Elsewhere on the Earth volcanic arcs dominantly consist of only two such chains. In the Kurile arc, magmatism in the third volcanic chain, which is farthest from the trench, is also unusual in that lavas show concentrations of incompatible elements intermediate between those of the two trenchward chains. This observation can be explained by relatively shallow segregation of primary magmas and high degrees of partial melting of magmas in the third chain, compared to the conditions of magma separation expected from a simple application of the general acrossarc variation. Initial magmas in such an atypical third chain may be produced by melting of K-amphibolebearing peridotite in the down-dragged layer at the base of the mantle wedge under anomalously hightemperature conditions. Such an unusual melting event may be associated with the particular tectonic setting of the Kamchatka region, i.e. the presence of subductiontransform boundary. Such a mechanism is consistent with the across-arc variation in Rb/K ratios in the Kamchatka lavas: lowest in the third chain rocks and highest in the second chain rocks. 相似文献
26.
Jiamin Wan Tolek Tyliszczak Tetsu K. Tokunaga 《Geochimica et cosmochimica acta》2007,71(22):5439-5449
Soils contain the largest inventory of organic carbon on the Earth’s surface. Therefore, it is important to understand how soil organic carbon (SOC) is distributed in soils. This study directly measured SOC distributions within soil microaggregates and its associations with major soil elements from three soil groups (Phaeozem, Cambisol, and Ultisol), using scanning transmission X-ray microscopy (STXM) and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy at a spatial resolution of 30 nm. Unlike previous studies, small intact soil microaggregates were examined directly in order to avoid preparatory procedures that might alter C speciation. We found that SOC exists as distinct particles (10s to 100s of nm) and as ubiquitous thin coatings on clay minerals and iron-oxides coatings. The distinct SOC particles have higher fractions of aromatic C than the coatings. NEXAFS spectra of the C coatings within individual microaggregates were relatively similar. In the Phaeozem soil, the pervasive spectral features were those of phenolic and carboxylic C, while in the Cambisol soil the most common spectral feature was the carboxyl peak. The Ultisol soil displayed a diffuse distribution of aromatic, phenolic, and carboxylic C peaks over all surfaces. In general, a wide range of C functional groups coexist within individual microaggregates. In this work we were able to, for the first time, directly quantify the major mineral elemental (Si, Al, Ca, Fe, K, Ti) compositions simultaneously with C distribution and speciation at the nm to μm scale. These direct microscale measurements will help improve understanding on SOC-mineral associations in soil environments. 相似文献
27.
Yasumasa Ogawa Daizo Ishiyama Naotatsu Shikazono Koichi Suto Chihiro Inoue Noriyoshi Tsuchiya Bernhardt Saini-Eidukat Scott A. Wood 《Aquatic Geochemistry》2018,24(1):5-25
This work assessed both the fractionation and the seasonal mobility variations of Ga and In in systems impacted by acidic thermal waters. This was accomplished by performing thermodynamic calculations using the PHREEQC algorithm and by assessing the activity of acidophilic iron-oxidizing bacteria. The pH of the Kusatsu thermal waters in Gunma Prefecture, central Japan, is rapidly increased following the addition of a lime suspension. After an abrupt pH increase, under which conditions free ions of Ga and In and their complexes with Cl? and SO42? exist only in negligible quantities, the majority of dissolved Ga and In is removed by sorption onto suspended hydrous ferric oxides (HFOs). These HFOs are then transported to an artificial lake without significant sedimentation along the river. Subsequently, the suspended HFOs settle out and are added to sediments without significant fractionation between Ga and In. The Tamagawa thermal waters in Akita Prefecture, northeast Japan, are also treated with lime. However, complete neutralization requires mixing with some tributary streams, leading to a gradual downstream increase in pH. Dissolved Ga is, in general, sorbed by HFOs in upstream areas, leading to wide dispersal of Ga across the entire watershed. In comparison, In is transported to the lake inlet predominantly as a Cl? complex species without significant removal along the river, with the majority being precipitated in an artificial lake, where Cl? concentrations are too low to form stable complex species with In, and thus, dissolved In is sorbed by HFOs. As a result, In is effectively concentrated within downstream lakebed sediments, whereas Ga is dispersed along the river. Seasonal variations in Ga mobility within the Tamagawa field between snowmelt and low-flow seasons are primarily controlled by pH, because hydrolysis reactions of these metals, which are related to sorption reactions, tend to occur in the upstream regions in the snowmelt season. However, under warmer conditions, HFO formation preferably occurs due to the activity of acidophilic iron-oxidizing bacteria. Thus, under similar pH variations, dissolved Ga is more effectively removed by HFOs during warmer seasons. On the contrary, because HFOs are abundantly formed in low-flow season, even under colder conditions, before In hydrolysis reaction starts to occur, In mobility is less affected by water temperature and then bacterial activity. 相似文献
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29.
Mohammad Reza Ghodsi Mohammad Boomeri Sasan Bagheri David Lentz Daizo Ishiyama 《Resource Geology》2016,66(3):286-302
The Mesozoic Bazman granitoids are located in Sistan and Baluchestan province, southeastern Iran. Geology of the study area consists of Carboniferous shale, sandstone, and limestone and Permian siltstone, shale, sandstone, limestone, and dolomite that were intruded by the Bazman granitoids. These granitoids include various phases of granite, granodiorite, quartz‐monzodiorite, monzodiorite, diorite, and gabbro. They are metaluminous to slightly peraluminous, reduced, calc‐alkaline and I‐type, and display geochemical characteristics of continental margin (ensialic) granitoids. In this paper, field, petrography, and geochemical data were used to discriminate the Bazman granitoids either as productive or barren granitoids. Although there are a few skarn‐related mineral occurrences adjacent to the Bazman granitoids, most exposed intrusions are not hydrothermally altered and mineralized. Rb/Sr, Zr/Hf, and K/Rb ratios indicate that the granitic magmas that formed most of the Bazman granitoids indicate that they are moderately evolved and have generally not undergone post‐magmatic hydrothermal activity. The Sm/Eu and Rb/Ba ratios and the concentrations of Rb, Ba, and Sr within the aforementioned granitoids show that the rocks are similar to the averages of granitoids devoid of Li, Be, U, Sn, W, and Ta deposits. The I‐type arc characteristics and other geochemical features of the Bazman granitoids show that they are not typical of parental magmas to Sn, W, Mo, and Zn mineralization, but are mainly fertile for Cu and Fe (Au) skarn‐related granitoids. 相似文献
30.
The collapse of marginally Jeans-unstable primordial gas clouds in the presence of a UV radiation field is discussed. Assuming that the dynamical collapse proceeds approximately in an isothermal self-similar fashion, we investigate the thermal evolution of the collapsing central core until H2 cooling dominates photoheating and the temperature drops to below 104 K. Consequently, the mass of the cooled core is evaluated as M cool =3.6×106 M⊙ ( I 21 /1)−0.32 . This scale depends only on the incident UV intensity, and provides a lower limit to the mass of collapsed objects in the UV radiation field. 相似文献